If you are looking to change the scode version from other than what Tealium has provided in the drop down list (like below image 1), if my understanding is correct, then you need to make changes in the tag template.
Steps to change custom scode/app measurement version:
After logging in, Click on your Initials at top right corner
Select Manage Templates
Select the respective Adobe Sitecatalyst Tag
IMPORTANT: Take a copy of the template before making any changes. Once saved you will not be able to rollback. Need to contact Tealium AM to get the old version.
Scroll down a bit and you will notice the scode/app measurement code starts.
Select the existing version on the code and replace it with your custom version.
you will find Tealium's other default codes and make sure you are not deleting any additional default codes other than the Sitecatalyst.
Save the template and close
Publish the changes
Note: If you are not comfortable doing the template changes please reach out Tealium AM who can help you engaging an Tealium support expert.
Hope this helps.
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do you mean when the website url is DEV environemnt and or PROD environment. IF you have the Tealium scripts setup properly across your dev environment and prod environment you can use a lookup data. Lookup match the ut.env and then match it with the correct reportsuite. Or if you have different website you can still use the lookup table so if domain equals "test.com" go to this report suite and so on. https://community.tealiumiq.com/t5/iQ-Tag-Management/Lookup-Table-Extension/ta-p/13708
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